Experimental and Computational Evaluation of Hybrid Bi₂O₃/WO₃ Nanoparticle-Filled Epoxy Composites for Lead-Free Tc-99m Gamma-Ray Shielding in Occupational Radiation Protection.

Abstract

Lead-free polymer composites containing high-atomic-number fillers are promising alternatives to conventional lead shielding for nuclear medicine applications. In this study, Bi₂O₃-, WO₃-, and hybrid Bi₂O₃/WO₃ nanoparticle-filled epoxy resin composites were fabricated and evaluated for attenuation of the 140 keV photons emitted by technetium-99m (Tc-99m). The synthesized Bi₂O₃ and WO₃ nanoparticles exhibited hydrodynamic diameters of 638.2 ± 11.3 and 404.2 ± 3.2 nm, respectively, with polydispersity indices below 0.30 and zeta potentials of -33.73 ± 0.63 and -32.47 ± 0.75 mV, indicating acceptable dispersion characteristics and colloidal stability. SEM-EDX confirmed successful incorporation of Bi- and W-containing phases into the epoxy matrix, while the XRD and FTIR analyses verified retention of the crystalline metal oxide phases and the principal chemical structure of the cured epoxy network. Tensile testing revealed a composition-dependent strength-ductility relationship, with the Bi₂O₃-filled composite exhibiting the highest tensile strength among the developed formulations and the hybrid composite showing the greatest elongation at break. XCOM and Phy-X/PSD simulations demonstrated that increasing high-Z filler content enhanced the mass and linear attenuation coefficients and reduced the half-value layer, tenth-value layer, and mean free path. Experimental shielding performance was evaluated using Hp(10) measurements with optically stimulated luminescence dosimeters positioned on an anthropomorphic thorax phantom under a fixed Tc-99m exposure geometry. The transmitted dose decreased with increasing filler loading, and nanoparticle-filled formulations generally outperformed the corresponding conventional-particle composites. The hybrid 75:25 Bi₂O₃/WO₃ NP composite exhibited the lowest mean Hp(10) value of 0.016 µSv, corresponding to a 50% reduction relative to the lead reference under the investigated geometry. The combined structural, mechanical, computational, and dosimetric results demonstrate that hybrid filler design enables simultaneous optimization of attenuation efficiency and mechanical tolerance. These findings identify the Bi-rich hybrid epoxy composite as a promising lead-free material for customized shielding components, including vial holders, syringe-shield housings, protective panels, and workstation accessories used during Tc-99m handling in nuclear medicine.